Chapter
2

Chemistry 210

Since x and t are independent variables, the only way a function of x and a function of t can be equal for all x and t is if they both equal a constant, say, 2 (this curious choice will become clearer below!). Then equating each side of the equation to 2 results in two equations, one in x and the other in t.

Our interest is in the x-dependent equation (i.e. the part that is independent of time). The equation in x is:

1 d2ψ(x)  = -β2
ψ(x)dx2

and hence we get

d2ψ(x)  + &beta2ψ(x) = 0
dx2

This is a time-independent classical wave equation. It is easy to solve, because all we have to do is take the β2sinψ(x) back over to the right hand side and then look for a function that, when we differentiate it twice, we get the same function again times 2. One solution would be sinβx, and another (remember Euler again) would be eβi...

The solution ψ(x) = Asinβx is equivalent to the time-dependent solution in Exercise 3.5 if we set t = 0 (check this for yourself). Hence we can identify β with 2π/λ, and we can then rewrite the time-independent wave equation in the form:

d2ψ(x)  +  4π2  &psi(x) = 0
dx2λ2

(13.17)