Chapter
2

Chemistry 210

Since x and t are independent variables, the only way a function of x and a function of t can be equal for all x and t is if they both equal a constant, say, -β2 (this curious choice will become clearer below!). Then equating each side of the equation to -β2 results in two equations, one in x and the other in t.

Our interest is in the x-dependent equation (i.e. the part that is independent of time). The equation in x is:

1 d2ψ(x)  = -β2
ψ(x)dx2

and hence we get

d2ψ(x)  + &beta2ψ(x) = 0
dx2

This is a time-independent classical wave equation. It is easy to solve, because all we have to do is take the β2sinψ(x) back over to the right hand side and then look for a function that, when we differentiate it twice, we get the same function again times -β2. One solution would be sinβx, and another (remember Euler again) would be eβi...

The solution ψ(x) = Asinβx is equivalent to the time-dependent solution in Exercise 3.5 if we set t = 0 (check this for yourself). Hence we can identify β with 2π/λ, and we can then rewrite the time-independent wave equation in the form:

d2ψ(x)  +  4π2  &psi(x) = 0
dx2λ2

(13.17)